The Pioneer Saturn Spacecraft, which began its journey as Pioneer 11, provided the first close view of the rings of Saturn as well as its system of moons. Its payload of 11 operating instruments obtained or confirmed data about the mass, temperature, composition, radiation belts, and atmosphere of the planet and its larger satellite, Titan. It made photometric and polarization measurements of lapetus, Rhea, Dione, and Tethys, as well as discovered additional rings. Scientific highlights of the mission are summarized. Color imagery provided by the photopolarimeter is included along with illustrations of the planet's magnetic field and radiation belts. Ames Research Center NASA-TM-80807